APPLICATIONS OF THE DIRECT CORRELATION FUNCTION SOLUTION THEORY TO THE THERMODYNAMICS OF FLUIDS AND FLUID MIXTURES
1 Thermodynamics and Its Concepts in Nonequilibrium 1 11 Introduction 6 12 General Concepts and Framework, Thermodynamic Systems, Processes, and the Universe 8 13 The First Law of Thermodynamics 14 14 The Second Law of Thermodynamics 18 References 29 2 Thermodynamics of Uniform Systems 35 21 Energy Balance, Entropy Inequality and Constitutive Principles, and Equations in Uniform Systems 35 22 Constitutive Equations of Uniform Fluids 41 23 Level of Description and Internal Variables 51 24 Uniform Reacting Mixture in Closed System 53 25 Phase Equilibria 60 References 63 3 Continuum Thermodynamics of Single Fluid 67 31 Kinematics of Continua 67 32 Change of Frame 74 33 Balances of Mass, Momentum, and Moment of Momentum 86 34 Energy Balance and Entropy Inequality 94 35 Constitutive Principles and Constitutive Equations for the Single Substance 98 36 Principle of Admissibility—Constitutive Equations of Single Material Fluid with Viscosity and Heat Conduction 104 37 Fluid with Linear Transport Properties 117 38 Equilibrium Processes in Linear Fluid 123 References 137 4 Continuum Thermodynamics of Mixture of Linear Fluids 143 41 Principles of Mixture Theory 143 42 Balances of Mass and Stoichiometry of Chemical Reactions 147 43 Balances of Momentum and Moment of Momentum in Reacting Mixture 155 44 Balance of Energy and Entropy Inequality in Reacting Mixture: Mixture Invariance 162 45 Chemically Reacting Mixture of Fluids with Linear Transport Properties 171 46 Thermodynamic Relationships in the Linear Fluid Mixture 184 47 Equilibrium in the Linear Fluid Mixture 208 48 Special Cases of Linear Fluid Mixtures Chemical Potentials and Activities 229 49 Chemical Reactions and their Kinetics 247 410 Transport Phenomena in the Linear Fluid Mixture 257 References 270