UNIT PROCESSES IN ORGANIC SYNTHESIS

By WILLIAM SANCHEZ

HYDRIDES AND DIHYDROGEN ACTIVATION THE REVERSIBLE ADDITION OF M H TO C X BONDS ON MODEL COMPLEXES OLE N A TYPICAL HOMOGENEOUSLY CATALYZED HYDROGENATION CYCLE THE WILKINSON CATALYST ISOMERIZATION OF ALKENES REACTIONS ON METAL SURFACES HETEROGENEOUSLY CATALYZED HYDROGENATION AND ISOMERIZATION HYDROTREATING IN PETROLEUM CHEMISTRY IMPORTANCE OF HYDROTREATING IN PETROLEUM THE CATALYTIC PROCESS COMPOSITION AND STRUCTURE OF HDS CATALYSTS MONO UNSATURATED FATTY ESTERS BY PARTIAL HYDROGENATION OF NATURAL OILS HYDROGENATION OF FATS THE SELECTIVITY PROBLEM NICKEL CATALYSTS AND CATALYTIC PROCESSES HYDROGENATION OF ADIPONITRILE TO THE USES OF HEXAMETHYLENEDIAMINE THE HYDROGENATION OF ADIPONITRILE INSIGHTS INTO THE REACTION MECHANISM MAKING L DOPA BY ENANTIOSELECTIVE HYDROGENATION OF ACETAMIDOARYLACRYLIC ACIDS THE DEVELOPMENT OF THE ENANTIOSELECTIVE MECHANISM OF THE ASYMMETRIC CATALYTIC ENANTIOSELECTIVE HYDROGENATION OF N ARYLIMINES IN THE SYNTHESIS OF THE CHIRAL HERBICIDE THE SYNTHESIS OF METOLACHLOR ISOMERIZATION REACTIONS DIETHYLGERANYLAMINE AND DIETHYLNERYLAMINE FOR THE PRODUCTION OF MENTHOL THE SYNTHETIC ROUTE TO MENTHOL ENANTIOSELECTIVE HYDROGEN TRANSFER ETHYLBENZENE DEHYDROGENATION TO STYRENE THE STYRENE MARKET ETHYLBENZENE NON OXIDATIVE CATALYSTS FOR ETHYLBENZENE DEHYDROGENATION MECHANISM AND DEACTIVATION ALTERNATIVES FOR NON OXIDATIVE CHAPTER SYNTHESES BASED ON CARBON MONOXIDE CARBONYLATION REACTIONS HISTORICAL AND SYNGAS AS A FEEDSTOCK THE WATER GAS SHIFT REACTION CARBONYLATION REACTIONS OF ALCOHOLS AND ESTERS MANUFACTURE OF ACETIC ACID FROM METHANOL ACETIC ACID HISTORICAL AND BACKGROUND COBALT CATALYZED CARBONYLATION OF METHANOL RHODIUM CATALYZED CARBONYLATION OF MECHANISM OF RHODIUM IODIDE CATALYZED IRIDIUM CATALYZED CARBONYLATION OF METHANOL MECHANISM OF THE IRIDIUM IODIDE CATALYZED RHODIUM CATALYZED CARBONYLATION OF METHYL ACETATE TO ACETIC ANHYDRIDE CARBONYLATION OF HIGHER ALCOHOLS HIGHER 4 2 10 CARBONYLATION OF BENZYL ALCOHOL TO PHENYLACETIC ACID MANUFACTURE OF IBUPROFEN HYDROXY ALKOXY CARBONYLATION ETHYLENE TO PROPIONIC ACID METHYL PROPIONATE AND METHYL METHACRYLATE MMA COBALT CATALYZED BUTADIENE DIMETHOXYCARBONYLATION TO DIMETHYL ADIPATE OXIDATIVE CARBONYLATION OF METHANOL TO DIMETHYL CARBONATE AND DIMETHYL OXALATE HYDROFORMYLATION OF OLE NS MANUFACTURE OF N BUTYRALDEHYDE AND UNMODI ED COBALT CATALYSTS PHOSPHINE MODI ED COBALT CATALYSTS RHODIUM CATALYZED HYDROFORMYLATION TWO PHASE WATER SOLUBLE RHODIUM RHODIUM HYDROFORMYLATION CATALYSTS WITH HYDROCARBONS FROM THE HYDROGENATION OF CO THE FISCHER TROPSCH F T REACTION FISCHER TROPSCH TECHNOLOGY CONCERNING THE MECHANISM OF THE FISCHER TROPSCH REACTION ANNEX 1 HOW ARE 1 ALKENES FORMED FROM SYNGAS OTHER MECHANISTIC PROPOSALS HOMOGENEOUS CO HYDROGENATION SOME HINTS FOR DISCUSSION POINTS CARBON CARBON BOND FORMATION ALKYLATION AND RELATED REACTIONS ETHYLBENZENE BY ALKYLATION OF BENZENE WITH TOLUENE DEALKYLATION AND METHYL REDISTRIBUTION TO BENZENE AND XYLENES CUMENE FROM BENZENE AND PROPYLENE 2 6 DI ISOPROPYLNAPHTHALENE OTHER ALKYLATIONS OF AROMATICS ALKANE CRACKING AND ISOMERIZATION ON SOLID O PENTENYLTOLUENE FROM O XYLENE AND C C BOND FORMATION THROUGH MULTIFUNCTIONAL CATALYSIS BY MIXED METAL CARBON CARBON BOND FORMATION THROUGH ACTIVATION OF ARYL OR VINYL HALIDE BONDS FINE CHEMICALS VINYLARENES BY VINYLATION OF AROMATICS ALKYNYLARENES BY VINYLATION OF TRIPLE BONDS BIARYLS BY ARYL COUPLING CONSIDERATIONS ON REACTIONS OF ARYL AND CHEMISTRY OF ALLYL COMPOUNDS BUTADIENE AS 1 4 HEXADIENE FROM BUTADIENE AND ETHYLENE CYCLOOCTADIENE AND CYCLODODECATRIENE FROM OCTADIENOL FROM BUTADIENE ADIPONITRILE BY HCN ADDITION TO BUTADIENE OLIGOMERIZATION OF OLE NS CARBENE CHEMISTRY AND ASYMMETRIC SYNTHESIS DEVISING NEW SYNTHETIC PATHWAYS HINTS TO IMPROVE OR TO DEVELOP ALTERNATIVE PROCESSES FOR THE SYNTHESIS OF AROMATICS CATALYZED BY TRANSITION METALS PERSPECTIVES IN C C BOND FORMING ANNEX 3 CATALYTIC E CIENCY AND SELECTIVITY REACTION MEDIA FOR CATALYSIS C H ACTIVATION METATHESIS OF OLE NS INTRODUCTION HISTORY AND BASIC CHEMISTRY OF THE CARBENE METALLACYCLOBUTANE MECHANISM OF INDUSTRIAL APPLICATIONS OF METATHESIS