COMPREHENSIVE ORGANIC SYNTHESIS
CONTENTS CHAPTER 1 CATALYTIC TANDEM REACTIONS TRIGGERED BY THE INTRODUCTION OF A CARBONYL FUNCTION INTRODUCTION OXIDATION/HETERONUCLEOPHILE ADDITION OXIDATION/C-NUCLEOPHILE ADDITION OXIDATION/SOPHISTICATED REACTIONS CARBONYL INSTALLATION/REACTIONS CONCLUSION CONSENT FOR PUBLICATION CONFLICT OF INTEREST ACKNOWLEDGEMENTS REFERENCES CHAPTER 2 SYNTHETIC APPLICATIONS OF BIFUNCTIONAL KNÖLKER TYPE IRON COMPLEXES AS (DE)HYDROGENATION CATALYSTS HYDROGENATION KNÖLKER’S IRON COMPLEX: DIRECT AND TRANSFER HYDROGENATION REACTIONS SWITCHING FE/OH COMPLEX TO FE/SIH COMPLEX: TRANSFER HYDROGENATION OF ALKYNE AND ALKENE IN SITU GENERATED KNÖLKER TYPE IRON COMPLEXES (CYCLOPENTADIENONE)IRON TRICARBONYL COMPLEXES: DIRECT HYDROGENATION OF CARBONYL COMPOUNDS HYDROGENATION NITRILE-LIGATED (CYCLOPENTADIENONE)IRON DICARBONYL COMPLEXES: HYDROGENATION OF CARBONYL COMPOUNDS HYDROGENATION UNDER WATER GAS SHIFT REACTION (WGSR) CONDITIONS (CYCLOPENTADIENONE)IRON TRICARBONYL COMPLEX: ALDEHYDE REDUCTION HETEROBIMETALLIC KNÖLKER TYPE COMPLEX: BENZALDEHYDE REDUCTION ASYMMETRIC HYDROGENATION CHIRAL IRON COMPLEXES: HYDROGENATION OF C=O BOND COMBINING ACHIRAL KNÖLKER’S COMPLEX AND CHIRAL ADDITIVE: HYDROGENATION OF C=N BOND DEHYDROGENATION KNÖLKER’S IRON COMPLEX: ALCOHOL DEHYDROGENATION (CYCLOPENTADIENONE) IRON COMPLEXES: ALCOHOL DEHYDROGENATION METHODS BASED ON DEHYDROGENATIVE ALCOHOL ACTIVATION BORROWING HYDROGEN METHODOLOGY CARBON-NUCLEOPHILE: CARBON-CARBON BOND FORMATION NITROGEN-NUCLEOPHILE: CARBON-NITROGEN BOND FORMATION HETEROCYCLE SYNTHESIS VIA C-C AND C-N BOND FORMATION DYNAMIC KINETIC RESOLUTION OF ALCOHOLS CONCLUDING REMARKS CHAPTER 3 SUPERELECTROPHILIC ACTIVATION OF ALKYNES, ALKENES, AND ALLENES SUPERELECTROPHILIC ACTIVATION OF ALKYNES SUPERELECTROPHILIC ACTIVATION OF ALKENES SUPERELECTROPHILIC ACTIVATION OF CONJUGATED ENYNONES SUPERELECTROPHILIC ACTIVATION OF ALLENES SUPERELECTROPHILIC ACTIVATION OF TRIFLUOROMETHYL SUBSTITUTED ALKYNES AND ALKENES CHAPTER 4 CHITOSAN AND ITS DERIVATIVES: SYNTHESIS STRATEGY AND APPLICATIONS SOURCE OF CHITIN AND CHITOSAN IN NATURE CHITOSAN PROPERTIES SYNTHESIS OF CHITOSAN DERIVATIVES CHITOSAN AND ITS DERIVATIVES: ANTIMICROBIAL ACTIVITY IMPORTANCE OF THE DEGREE OF DEACETYLATION (DD) OF CHITOSAN ANTIMICROBIAL ACTION BY CHELATING CAPACITY OF CHITOSAN TOXICITY OF CHITOSAN AND CHITOSAN DERIVATIVES ENVIRONMENTAL APPLICATION OF CHITOSAN - DERIVATIVES ENTRAPMENT OF BACTERIAL STRAINS INTO CHITOSAN BEADS FOR BIOREMEDIATION APPLICATION ENTRAPMENT OF CELLS IN CHITOSAN BEADS CHITOSAN/DERIVATIVES FOR THE BIOREMEDIATION OF OIL-POLLUTED SEAWATER CHITOSAN: ALTERNATIVE APPLICATION AS COAGULATION AID CHITOSAN/METAL OXIDES NANOCOMPOSITES CHITOSAN: A VERSATILE BIOCOMPATIBLE POLYMER CHAPTER 5 SYNTHESIS OF N-CONTAINING HETEROCYCLES VIA HYPERVALENT IODINE(III)-MEDIATED INTRAMOLECULAR OXIDATIVE CYCLIZATION THREE-MEMBERED RING 2H-AZIRINE AZIRIDINE FOUR-MEMBERED RING ALEKSANDER V VASILYEV AZETIDINES FOUR-MEMBERED ?-LACTAM FIVE-MEMBERED RING PYRROLE DERIVATIVES INDOLE DERIVATIVES AZOLES SIX-MEMBERED RING SEVEN-MEMBERED RING SPIRO- AND FUSED- HETEROCYCLES CONCLUSION AND FUTURE PERSPECTIVE ACKNOWLEDGEMENT CHAPTER 6 ADVANCEMENTS IN IONIC LIQUIDS FOR THE FORMATION OF MORITA BAYLIS-HILLMAN ADDUCTS ORIGIN AND FEATURES OF MORITA BAYLIS-HILLMAN REACTION PRESENT STATUS IN CONTEXT TO IONIC LIQUIDS IMIDAZOLIUM-BASED IONIC LIQUIDS