EXPERIMENTAL ORGANIC CHEMISTRY
IODINE AS A CATALYST FOR ISOMERIZATION ASSESSING PURITIES OF DIMETHYL MALEATE AND FUMARATE PROPERTIES OF THE ENANTIOMERS OF CARVONE PROPERTIES OF THE ENANTIOMERIC CARVONES POLARIMETRY RESOLUTION OF RACEMIC 1-PHENYLETHANAMINE MINISCALE PROCEDURE HISTORICAL HIGHLIGHT: DISCOVERY OF STEREOISOMERS CHAPTER SPECTRAL METHODS INTRODUCTION INFRARED (IR) SPECTROSCOPY NUCLEAR MAGNETIC RESONANCE (NMR) SPECTROSCOPY ULTRAVIOLET AND VISIBLE SPECTROSCOPY MASS SPECTROMETRY HISTORICAL HIGHLIGHT: MEDICAL DIAGNOSTICS VIA NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY ALKANES CHLORINATION USING SULFURYL CHLORIDE FREE-RADICAL CHAIN CHLORINATION OF L-CHLOROBUTANE MICROSCALE PROCEDURE CHLORINATION OF HEPTANE CHLORINATION OF 2,3-DIMETHYLBUTANE BROMINATION: SELECTIVITY OF HYDROGEN ATOM ABSTRACTION RELATIVE RATES OF FREE-RADICAL CHAIN BROMINATION HISTORICAL HIGHLIGHT: KEEPING IT COOL ALKENES DEHYDROHALOGENATION OF ALKYL HALIDES BASE-PROMOTED ELIMINATION OF AN ALKYL HALIDE A ELIMINATION WITH ALCOHOLIC POTASSIUM HYDROXIDE B ELIMINATION WITH POTASSIUM TERT-BUTOXIDE ELIMINATION OF ALTERNATE NON-TERMINAL ALKYL HALIDES DEHYDRATION OF ALCOHOLS A DEHYDRATION OF 4-METHYL-2-PENTANOL B DEHYDRATION OF CYCLOHEXANOL ELIMINATION OF STEREOISOMERIC ALCOHOLS ADDITION REACTIONS OF ALKENES: OVERVIEW ADDITION OF HYDROBROMIC ACID TO ALKENES ADDITION OF HYDROGEN BROMIDE TO 1-HEXENE ANALYSIS OF BROMOHEXANES BROMINATION OF ALKENES BROMINATION OF (E)-STILBENE BROMINATION OF (E)-STILBENE: THE GREEN APPROACH BROMINATION OF (Z)-STILBENE SOLVENT EFFECTS ON THE STEREOCHEMISTRY OF BROMINATION SUBSTITUENT EFFECTS ON THE STEREOCHEMISTRY OF BROMINATION ACID-CATALYZED HYDRATION OF ALKENES HYDRATION OF NORBORNENE HYDROBORATION-OXIDATION OF ALKENES HYDROBORATION-OXIDATION OF (+)--PINENE REGIOCHEMISTRY OF HYDROBORATION/OXIDATION OF AN ACYCLIC ALKENE REGIO- AND STEREOCHEMISTRY OF HYDROBORATION/ OXIDATION OF A CYCLOPENTENE HISTORICAL HIGHLIGHT: ADDITIONS ACROSS CARBON-CARBON -BONDS ALKYNES DEHYDROHALOGENATION OF 1,2-DIHALOALKANES DEHYDROBROMINATION OF MESO-STILBENE DIBROMIDE MINISCALE PROCEDURE FOR MICROWAVE OPTION ADDITION REACTIONS OF ALKYNES PREPARATION OF 3-HYDROXY-3-METHYL-2-BUTANONE TERMINAL ALKYNES AS ACIDS FORMATION OF A SILVER ACETYLIDE AND ITS DECOMPOSITION HISTORICAL HIGHLIGHT: ACETYLENE: A VALUABLE SMALL MOLECULE DIENES: THE DIELS-ALDER REACTION MECHANISTIC AND STEREOCHEMICAL ASPECTS APPLICATIONS OF DIELS-ALDER REACTIONS DIELS-ALDER REACTION A REACTION OF 1,3-BUTADIENE AND MALEIC ANHYDRIDE B REACTION OF 1,3-CYCLOPENTADIENE AND MALEIC ANHYDRIDE C HYDROLYSIS OF ANHYDRIDES 1 4-CYCLOHEXENE-CIS-1,2-DICARBOXYLIC ACID MINISCALE PROCDURE MICROSCALE PROCDURE 2 BICYCLO[2 2 1]HEPT-5-ENE-ENDO-2,3-DICARBOXYLIC ACID HYDROLYSIS OF ANHYDRIDES HISTORICAL HIGHLIGHT: DISCOVERY OF THE DIELS-ALDER REACTION KINETIC AND THERMODYNAMIC CONTROL OF A REACTION FORMATION OF SEMICARBAZONES UNDER KINETIC AND THERMODYNAMIC CONTROL A PREPARATION OF CYCLOHEXANONE SEMICARBAZONE B PREPARATION OF 2-FURALDEHYDE SEMICARBAZONE C REACTIONS OF SEMICARBAZIDE WITH CYCLOHEXANONE AND 2-FURALDEHYDE IN PHOSPHATE BUFFER SOLUTION D REACTIONS OF SEMICARBAZIDE WITH CYCLOHEXANONE AND 2-FURALDEHYDE IN BICARBONATE BUFFER SOLUTION E TESTS OF REVERSIBILITY OF SEMICARBAZONE FORMATION EFFECT OF PH ON KINETIC VS THERMODYNAMIC CONTROL