THE ELEMENTARY PRINCIPLES OF CHEMISTRY

By JESSICA MARTINEZ

CONTENTS CHAPTER WHAT SOME CHEMICAL ENGINEERS DO FOR A LIVING CHAPTER INTRODUCTION TO ENGINEERING CALCULATIONS CHAPTER PROCESSES AND PROCESS VARIABLES INSTRUCTIONAL OBJECTIVES UNITS AND DIMENSIONS CONVERSION OF UNITS SYSTEMS OF UNITS FORCE AND WEIGHT NUMERICAL CALCULATION AND ESTIMATION DIMENSIONAL HOMOGENEITY AND DIMENSIONLESS QUANTITIES PROCESS DATA REPRESENTATION AND ANALYSIS SUMMARY PROBLEMS MASS AND VOLUME FLOW RATE CHEMICAL COMPOSITION PRESSURE TEMPERATURE PART ENGINEERING PROBLEM ANALYSIS CHAPTER FUNDAMENTALS OF MATERIAL BALANCES CHAPTER SINGLE-PHASE SYSTEMS CHAPTER MULTIPHASE SYSTEMS CHAPTER ENERGY AND ENERGY BALANCES PROCESS CLASSI?CATION BALANCES MATERIAL BALANCE CALCULATIONS BALANCES ON MULTIPLE-UNIT PROCESSES RECYCLE AND BYPASS CHEMICAL REACTION STOICHIOMETRY BALANCES ON REACTIVE PROCESSES COMBUSTION REACTIONS SOME ADDITIONAL CONSIDERATIONS ABOUT CHEMICAL PROCESSES LIQUID AND SOLID DENSITIES IDEAL GASES EQUATIONS OF STATE FOR NONIDEAL GASES THE COMPRESSIBILITY FACTOR EQUATION OF STATE SINGLE-COMPONENT PHASE EQUILIBRIUM THE GIBBS PHASE RULE GAS–LIQUID SYSTEMS: ONE CONDENSABLE COMPONENT MULTICOMPONENT GAS–LIQUID SYSTEMS SOLUTIONS OF SOLIDS IN LIQUIDS EQUILIBRIUM BETWEEN TWO LIQUID PHASES ADSORPTION ON SOLID SURFACES FORMS OF ENERGY: THE FIRST LAW OF THERMODYNAMICS KINETIC AND POTENTIAL ENERGY ENERGY BALANCES ON CLOSED SYSTEMS CONTENTS PART MATERIAL BALANCES PART ENERGY BALANCES CHAPTER BALANCES ON NONREACTIVE PROCESSES CHAPTER BALANCES ON REACTIVE PROCESSES CHAPTER COMPUTER-AIDED BALANCE CALCULATIONS CHAPTER BALANCES ON TRANSIENT PROCESSES ENERGY BALANCES ON OPEN SYSTEMS AT STEADY STATE TABLES OF THERMODYNAMIC DATA ENERGY BALANCE PROCEDURES MECHANICAL ENERGY BALANCES ELEMENTS OF ENERGY BALANCE CALCULATIONS CHANGES IN PRESSURE AT CONSTANT TEMPERATURE CHANGES IN TEMPERATURE PHASE CHANGE OPERATIONS MIXING AND SOLUTION HEATS OF REACTION MEASUREMENT AND CALCULATION OF HEATS OF REACTION: HESS’S LAW FORMATION REACTIONS AND HEATS OF FORMATION HEATS OF COMBUSTION ENERGY BALANCES ON REACTIVE PROCESSES FUELS AND COMBUSTION DEGREE-OF-FREEDOM ANALYSIS REVISITED SEQUENTIAL MODULAR SIMULATION EQUATION-BASED SIMULATION COMMERCIAL PROCESS SIMULATION PACKAGES FINAL CONSIDERATIONS THE GENERAL BALANCE EQUATION AGAIN MATERIAL BALANCES ENERGY BALANCES ON SINGLE-PHASE NONREACTIVE PROCESSES SIMULTANEOUS TRANSIENT BALANCES CONTENTS CHAPTER PRODUCTION OF CHLORINATED POLYVINYL CHLORIDE CHAPTER STEAM REFORMING OF NATURAL GAS AND SUBSEQUENT SYNTHESIS OF METHANOL CHAPTER SCRUBBING OF SULFUR DIOXIDE FROM POWER PLANT STACK GASES PVC CHLORINATION REACTION CHEMISTRY PROCESS DESCRIPTION CONTENTS PART CASE STUDIES