THE BIOCHEMISTRY OF ALKALOIDS
1 Introduction | 1 11 Summary on natural organic compounds | 1 12 Proton nuclear magnetic resonance spectroscopy implicated in structures of NOCs | 3 121 Definition of chemical shift | 4 122 Manifestation and influencing factors of chemical shift | 5 123 Spin-spin coupling and spin-spin splitting | 7 124 Coupling constants | 9 2 Alkaloids | 11 21 Pyrrolidine alkaloids | 11 211 Polyhydroxylated pyrrolidine alkaloids | 11 212 Stemona alkaloids | 19 22 Tropane alkaloids | 30 221 Tropanol-type tropane alkaloids | 30 222 Hyoscyamine-type tropane alkaloids | 32 223 Dimeric tropane alkaloids | 38 23 Pyrrolizidine alkaloids | 41 24 Piperidine alkaloids | 49 241 N-acyl piperidine alkaloids | 49 242 Short-chain substituted piperidine alkaloids | 52 243 Long-chain substituted piperidine alkaloids | 57 244 Chromone-type piperidine alkaloids | 60 245 Alkaloids containing piperidine moiety in molecular structure | 62 246 Coupled piperidine alkaloids | 64 25 Licopodium alkaloids | 67 251 Licopodine-type licopodium alkaloids | 67 252 Lycodine-type licopodium alkaloids | 74 253 Fawcettimine-type licopodium alkaloids | 79 254 Other licopodium alkaloids | 87 26 Indolizidine alkaloids | 96 27 Quinolizidine alkaloids | 118 271 Lupinine-type alkaloids | 118 272 Sparteine-type alkaloids | 128 273 Cytisine-type alkaloids | 136 274 Matrine-type alkaloids | 138 28 Acridone alkaloids | 141 29 Amphetamine alkaloids | 152 291 Amine-type amphetamine alkaloids | 152 292 Amide-type amphetamine alkaloids | 152 293 Imine-type amphetamine alkaloids | 153 210 Isoquinoline alkaloids | 155 2101 Benzylated isoquinoline alkaloids | 155 2102 Dimeric benzylated isoquinoline alkaloids | 160 2103 Morphine-type isoquinoline alkaloids | 173 2104 Aporphine-type isoquinoline alkaloids | 181 2105 Protoberberine-type, dihydroberberine-type, berberine-type isoquinoline alkaloids | 193 2106 Protopine-type isoquinoline alkaloids | 200 2107 Benzophenanthridine-type isoquinoline alkaloids | 202 211 Phenylethylated tetrahydroisoquinoline alkaloids | 212 2111 Colchicine-type phenylethylated tetrahydroisoquinoline alkaloids | 212 2112 Homoerythrine-type phenylethylated tetrahydroisoquinoline alkaloids | 215 2113 Cephalotaxine-type phenylethylated tetrahydroisoquinoline alkaloids | 217 2114 1-phenylethyl-tetrahydroisoquinoline-type alkaloids | 225 2115 Homoaporphine-type alkaloids | 227 212 Benzylated phenethylamine alkaloids | 229 2121 Lycorine-type benzylated phenethylamine alkaloids | 229 2122 Crinine-type benzylated phenethylamine alkaloids | 233 2123 Galanthamine-type benzylated phenethylamine alkaloids | 244 2124 Tazettine-type benzylated phenethylamine alkaloids | 246 2125 Narciclasine-type benzylated phenethylamine alkaloids | 249 2126 Lycorenine-type benzylated phenethylamine alkaloids | 250 2127 Other benzylated phenethylamine alkaloids | 255 213 Emetine-type alkaloids | 261 214 Carboline alkaloids | 276 215 Semiterpenoid indole (or ergoline) alkaloids | 285 2151 Clavine-type semiterpenoid indole alkaloids | 285 2152 Lysergic acid-type semiterpenoid indole alkaloids | 285 2153 Secoergoline-type semiterpenoid indole alkaloids | 287 216 Monoterpenoid indole alkaloids | 288 2161 Monomeric monoterpenoid indole alkaloids | 288 2162 Dimeric monoterpenoid indole alkaloids | 297 2163 Other monoterpenoid indole alkaloids | 302 217 Quinoline alkaloids | 306 2171 2-oxo-type quinoline alkaloids | 306 2172 4-oxo-type quinoline alkaloids | 311 2173 Quinolinopyran-type quinoline alkaloids | 318 2174 Quinolinofuran-type quinoline alkaloids | 321 2175 Decahydroquiniline-type quinoline alkaloids | 328 2176 Other quinoline alkaloids | 331 218 Peptide alkaloids | 335 219 Monoterpenoid alkaloids | 340 2191 Pyridine monoterpenoid alkaloids | 340 2192 Piperidine monoterpenoid alkaloids | 342 2193 Tetrahydropyridine monoterpenoid alkaloids | 347 2194 Pyridinolactam monoterpenoid alkaloids | 349 2195 Pyridino-?-lactone monoterpenoid alkaloids | 349 220 Sesquiterpenoid alkaloids | 351 2201 Dendrobine-type sesquiterpenoid alkaloids | 351 2202 Nupharidine-type sesquiterpenoid alkaloids | 352 2203 Dihydro-?-agarofuran-type sesquiterpenoid alkaloids | 352 221 Diterpenoid alkaloids | 357 2211 A1-type diterpenoid alkaloids | 357 2212 A2-type diterpenoid alkaloids | 361 2213 B1-type diterpenoid alkaloids | 365 2214 B2-type diterpenoid alkaloids | 385 2215 B5-type diterpenoid alkaloids | 394 2216 B6-type diterpenoid alkaloids | 395 2217 C1-type diterpenoid alkaloids | 396 2218 C2-type diterpenoid alkaloids | 401 2219 C3-type diterpenoid alkaloids | 404 22110 C4-type diterpenoid alkaloids | 407 22111 C5-type diterpenoid alkaloids | 414 22112 C6-type diterpenoid alkaloids | 416 22113 C8-type diterpenoid alkaloids | 417 22114 C10-type diterpenoid alkaloids | 418 22115 M-type diterpenoid alkaloids | 419 222 Triterpenoid alkaloids | 425 2221 Daphniphylline-type triterpenoid alkaloids | 425 2222 Secodaphniphylline-type triterpenoid alkaloids | 428 2223 Yuzurimine-type triterpenoid alkaloids | 431 2224 Daphnilactone-type triterpenoid alkaloids | 437 2225 Yuzurine-type triterpenoid alkaloids | 439 2226 Daphnicyclidine-type triterpenoid alkaloids | 443 2227 Calyciphylline-type triterpenoid alkaloids | 446 2228 Paxdaphnine A-type triterpenoid alkaloids | 452 223 C21-pregnane alkaloids | 456 2231 Saracodine-type C21-pregnane alkaloids | 456 2232 Pachysine-type C21-pregnane alkaloids | 460 224 Cycloregnane alkaloids | 462 225 Cholestane and stigmastane alkaloids | 466 2251 Cholestane-type alkaloids | 466 2252 Stigmastane-type alkaloids | 469 226 Quinazoline alkaloids | 473